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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 19
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Original Articles

Novel Synthesis of Ethynyl Vinyl Carbinols and 2,5-Disubstituted Furans from Aldehydes

Zoltan G. Hajos R.W. Johnson Pharmaceutical Research Institute at Ortho Pharmaceutical Corporation, Raritan, New Jersey, 08869
,
Michael P. Wachter R.W. Johnson Pharmaceutical Research Institute at Ortho Pharmaceutical Corporation, Raritan, New Jersey, 08869
&
Harvey M. Werblood R.W. Johnson Pharmaceutical Research Institute at Ortho Pharmaceutical Corporation, Raritan, New Jersey, 08869
Pages 3295-3300 | Received 12 Jun 1989, Published online: 24 Oct 2006
 
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Abstract

Gem-substituted aryl, aralkenyl and 2-furyl ethynyl vinyi carbinols as well as 2,5-disubstituted furans can be obtained by a novel addition and rearrangement reaction of acetylene with the appropriate aldehydes.

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