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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 19
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Original Articles

Selective Oxidative Cleavage of Benzylic Carbon-Nitrogen Double Bonds Under Non-Aqueous Condition with Tetrakis(pyridine)-Silver Dichromate [(Py)2Ag]2 Cr2O7

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Pages 3385-3395 | Received 03 Jul 1989, Published online: 24 Oct 2006
 

Abstract

Carbonyl derivatives of phenylhydrazine, 2-nitrophenylhydrazine, 2, 4-dinitrophenazine, semicarbozone, and hydroxylamine are converted to their corresponding carbonyl compounds with tetrakis(pyridine)silver dichromate in benzene. Selectivity is also observed for benzylic C = N cleavage.

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