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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 20
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Original Articles

A Convenient Synthesis of Allyltrimethylsilanes from Allylic Phosphates

Janice Gorzynski Smith Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Susan L. Henke Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Elizabeth M. Mohler Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Linda Morgan Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
&
N. Ivy Rajan Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
Pages 1999-2006 | Received 22 May 1991, Published online: 23 Sep 2006
 
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Abstract

Treatment of an allylic phosphate with trimethylsilyllithium or trimethylsilylcopper [prepared from one equivalent of trimethylsilyllithium and copper(I) iodide] affords allyltrimethylsilanes in good - excellent yields with high stereoselectivity.

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