Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 20
Submit an article Journal homepage
99
Views
7
CrossRef citations to date
0
Altmetric
Original Articles

A Convenient Synthesis of Allyltrimethylsilanes from Allylic Phosphates

Janice Gorzynski Smith Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Susan L. Henke Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Elizabeth M. Mohler Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
,
Linda Morgan Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
&
N. Ivy Rajan Department of Chemistry, Carr Laboratory, Mount Holyoke College, South Hadley, Massachusetts, 01075
Pages 1999-2006 | Received 22 May 1991, Published online: 23 Sep 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Treatment of an allylic phosphate with trimethylsilyllithium or trimethylsilylcopper [prepared from one equivalent of trimethylsilyllithium and copper(I) iodide] affords allyltrimethylsilanes in good - excellent yields with high stereoselectivity.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.