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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 2
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Original Articles

Selenium Dioxide Oxidation of Steroidal 1,4-Dien-3-Ones. A Simple and Convenient Route to 6-Hydroxycorticosteroids

Tadao Terasawa Shionogi Research Laboratories, Shionogi & Co., Ltd., Fukushima-ku, Osaka, 553, Japan
&
Toshihiko Okada Shionogi Research Laboratories, Shionogi & Co., Ltd., Fukushima-ku, Osaka, 553, Japan
Pages 307-317 | Received 01 Dec 1990, Published online: 23 Sep 2006
 
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Abstract

A convenient one-step procedure for the chemical synthesis of 6-hydroxycorticosteroids involving allylic oxidation by selenium dioxide is described.

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