A Novel Chiral Auxiliary for Enantioselective Synthesis of Tertiary Alcohol

Brindaban C. Ranu Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, India

Rupak Chakraborty Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, India

Dipak C. Sarkar Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, India

Abstract

The use of 1-menthyl ester of 1,3-dithiane-2-carboxylic acid as a chiral auxilary for the conversion of acetophenone, propiophenone and butyrophenone to the corresponding optically active tertiary alcohols 2-phenylhexan-2-ol, 3-phenylheptan-3-ol and 4-phenyloctan-4-ol, has been demonstrated.

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A Novel Chiral Auxiliary for Enantioselective Synthesis of Tertiary Alcohol

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A Novel Chiral Auxiliary for Enantioselective Synthesis of Tertiary Alcohol

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