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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 6
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Original Articles

Selective Oxidation of 6-Propionylflavonols and 6-Propionyl-2-Hetarylchromdnols Using Hypervalbnt Iodine Reagents in Methanol

Mahavir S Khanna Department of Chemistry, Kurukshetra University, Kurukshetra, 132 119, INDIA
,
Km Sangeeta Department of Chemistry, Kurukshetra University, Kurukshetra, 132 119, INDIA
,
Chandra P Garg Department of Chemistry, Kurukshetra University, Kurukshetra, 132 119, INDIA
&
Ram P Kapoor Department of Chemistry, Kurukshetra University, Kurukshetra, 132 119, INDIA
Pages 893-900 | Received 01 Oct 1991, Published online: 23 Sep 2006
 
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Abstract

Selective oxidation of 6-propionyl flavonols (1a-d) and 6-propionyl-2-hetarylchromonols (1e-f) to 2,3-dimethoxy-3-hydroxy-6-propionylf lavanones (2a-d) and 2,3-dimethoxy-3-hydroxy-6-propiony1-2-hetarylchromanones (2e-f), respectively, using [bis(trifluoroacetoxy)iodo]benzene(BTFAIB), [hydroxy(tosyloxy)-iodo] benzene (HTIB), iodobenzene diacetate (IBD) and iodosylbenzene (IB) in methanol has been described.

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