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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 6
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Original Articles

Regioselective Synthesis of 4-(Aryloxymethyl)Thiopyrano [2,3-B][1]Benzothiopyran-5(2H)-Ones

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Pages 901-912 | Received 03 Oct 1991, Published online: 23 Sep 2006
 

Abstract

Phase transfer catalysed alkylation of 4-hydroxy dithiocoumarin (3) with a number of 1-aryloxy-4-chloro-but-2-ynes (4) furnished several 2-(4′-aryloxy-but-2′-ynyl thio)-[1]-benzothiopyran-4-ones (5) which when heated in chlorobenzene gave hitherto unreported 4-(aryloxymethyl)thiopyrano[2,3-b] benzothiopyran-5(2H)-ones (2) in excellent yields.

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