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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 20
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Original Articles

Stereoselective Synthesis of 7-Methylhexadec-6-enoic Acid, a Component of Carribean Sponge

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Pages 2921-2925 | Received 01 Jun 1992, Published online: 23 Sep 2006
 

Abstract

The marine natural product (E)-7-methyl hexadec-6-enoic acid(I), has been synthesised for the first time starting from commercially available methyl vinyl ketone. Stereoselective generation of its tri- substituted olefinic moiety is accomplished via Claisen orthoester rearrangement.

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