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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 11
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Original Articles

Facile Conversion of Tosylhydrazones to Carbonyl Compounds by the Potassium Peroxymonosulfate-Acetone System

Jae Chul Jung Department of Chemistry, Korea Advanced Institute of Science and Technology, P.O. Box 150, Cheongyang-Ni, Seoul, 130-650, Korea
,
Kyoung Soo Kim Department of Chemistry, Korea Advanced Institute of Science and Technology, P.O. Box 150, Cheongyang-Ni, Seoul, 130-650, Korea
&
Yong Hae Kim Department of Chemistry, Korea Advanced Institute of Science and Technology, P.O. Box 150, Cheongyang-Ni, Seoul, 130-650, Korea
Pages 1583-1587 | Accepted 24 Jan 1992, Published online: 23 Sep 2006
 
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Abstract

Tosylhydrazones of carbonyl compounds were found to be readily cleaved into the corresponding carbonyl compounds in good yields under the mild conditions by treatment with dimethyldioxirane which is generated in situ from the reaction of acetone with potassium peroxymonosulfate.

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