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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 21
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Original Articles

Novel Syntheses of Heterocycles with N-(1-Haloalkyl)Azinium Halides. Part 4. An Unexpected One-Pot Preparation of 1H-Perimidines

Jean-Jacques Vanden Eynde Organic Chemistry Laboratory University of Mons-Hainaut, B - 7000, Mons, Belgium
,
Annie Mayence Organic Chemistry Laboratory University of Mons-Hainaut, B - 7000, Mons, Belgium
,
André Maquestiau Organic Chemistry Laboratory University of Mons-Hainaut, B - 7000, Mons, Belgium
&
Ernst Anders Institut für Organische Chemie Universität Erlangen-Nurnberg, D - 8520, Erlangen, Germany
Pages 3141-3150 | Received 29 Jun 1992, Published online: 01 Apr 2009
 
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Abstract

Reactions between N-(1-haloalkyl) pyridinium chlorides and 1, 8-naphthalenediamine yield 1H-perimidines only when the salts are not isolated. When they are isolated, formation of the 2, 3-dihydro derivatives is observed.

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