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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 5
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Original Articles

A Novel Route to Substituted Trienes and Tetraenes

Tomasz Janecki Institute of Organic Chemistry, Technical University, Zwirki 36, 90-924, Łódz, Poland
Pages 641-650 | Received 14 Sep 1992, Published online: 27 Oct 2006
 
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Abstract

The reaction sequence involving Arbuzov rearrangement of allyl phosphites 4 to phosphonates 5 followed by Horner-Wadsworth-Emmons olefination of 5 with aldehydes gives substituted trienes and tetraenes 8 with full stereoselectivity.

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