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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 12
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Original Articles

Synthesis and Reactivity of the New Chiral Silylphosphite Esters {(+)-O, O-Dimethyl-L-tartrate}POSiR3 (R3 = Ph3, tBuMe2, Et3)

I. Frazer Pickersgill School of Chemistry, University of Leeds, Leeds, LS2 9JT, U.K.
,
Paul G. Devitt School of Chemistry, University of Leeds, Leeds, LS2 9JT, U.K.
&
Terence P. Kee School of Chemistry, University of Leeds, Leeds, LS2 9JT, U.K.
Pages 1643-1650 | Received 18 Dec 1992, Published online: 23 Sep 2006
 
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Abstract

The new, chiral silylphosphite compounds (O,O-dimethyl-L-tartrato)POSiR3, (R3 = Ph3, tBuMe2, Et3) have been synthesised and their activity as asymmetric phosphonylating reagents investigated.

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