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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 12
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Original Articles

Lithium Aluminum Amides: New Reagents for the Synthesis of Imines

Arlette Solladié-Cavallo Laboratoire de Stéréochimie Organométallique associé au CNRS, EHICS, 1 Rue B. Pascal, 67008, Strasbourg, France
,
Mohamed Bencheqroun Laboratoire de Stéréochimie Organométallique associé au CNRS, EHICS, 1 Rue B. Pascal, 67008, Strasbourg, France
&
Frédeérique Bonne Laboratoire de Stéréochimie Organométallique associé au CNRS, EHICS, 1 Rue B. Pascal, 67008, Strasbourg, France
Pages 1683-1687 | Received 08 Jan 1993, Published online: 23 Sep 2006
 
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Abstract

Aldehydes (4 eqiv.) react under mild conditions with LiA1(NHR1)4 (1 eqiv.) to give the corresponding imines in 90% yield and no polymerization was observed upon reaction of aliphatic aldehyde3.

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