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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 23, 1993 - Issue 18
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Original Articles

One Pot Synthesis of 2,6-Dichloro-3,5-dicyanopyridine from Aliphatic Precursors

, &
Pages 2605-2609 | Received 14 Apr 1993, Published online: 24 Sep 2006
 

Abstract

Malononitrile is condensed with triethyl orthoformate in the presence of pyridine; the mixture is acidified with HCI gas and after addition of further pyridime. HCI diazotised to form 2,6-dichloro-3,5-dicyanopyridine in a convenient, high yield process.

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