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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 24, 1994 - Issue 12
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Original Articles

Synthesis and Mercury (II) Trifluoroacetate Mediated Cyclization of N-Aryl -Allenylmethyl Carbamide

B. Devan Department of Organic Chemistry, University of Madras, Guindy Campus, Madras, 600 025, INDIA
&
K. Rajagopalan Department of Organic Chemistry, University of Madras, Guindy Campus, Madras, 600 025, INDIA
Pages 1691-1700 | Received 11 Nov 1993, Published online: 23 Sep 2006
 
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Abstract

A three step sequence is described for conversion of substituted phenyl carbamide into 1-cyano-4-methylidene -1,2,3,4-tetrahydro quinoline involving N-propargylation, allene formation followed by mercury (II) trifluoro acetate catalysed cyclization.

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