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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 24, 1994 - Issue 6
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Original Articles

Palladium-Catalyzed Coupling of Stannyl Allenes With Aryl Iodides

Indrapal Singh Aidhen Department of Chemistry and Biochemistry, University of California, Santa Cruz, Santa Cruz, California, 95064
&
Rebecca Braslau Department of Chemistry and Biochemistry, University of California, Santa Cruz, Santa Cruz, California, 95064
Pages 789-797 | Received 26 Jul 1993, Published online: 16 Feb 2007
 
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Abstract

Substituted allenes are prepared by coupling stannyl allenes with aryl iodides under palladium(O) catalysis. A concise and versatile sequence starting from propargyl alcohols provides a route for the preparation of substituted allenes under extremely mild conditions.

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