Extended Chains of Six-Membered Rings 1. Model Studies and Key Intermediates

Robert M. Cory Department of Chemistry, University of Western Ontario, London, Ontario, Canada, N6A 5B7

Jeffrey R. Walker Department of Chemistry, University of Western Ontario, London, Ontario, Canada, N6A 5B7

Pierre D. Zabel Department of Chemistry, University of Western Ontario, London, Ontario, Canada, N6A 5B7

Abstract

McMurry coupling of 4-phenylcyclohex-3-en-1-one and double addition of 1,4-dilithiobenzene and 4,4′-dilithiobiphenyl to cyclohexanones gives linear chains of three or four six-membered carbocyclic rings, including a potential intermediate in a proposed synthesis of [O₆]paracyclophane.

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Extended Chains of Six-Membered Rings 1. Model Studies and Key Intermediates

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Extended Chains of Six-Membered Rings 1. Model Studies and Key Intermediates

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