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Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 25, 1995 - Issue 12

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Original Articles

A Convenient One-Step Catalytic Method for Obtaining Optically Active 2-Cyclopentenyl Benzoate from Cyclopentene

Aviva Levina Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France

Jacques Muzart Unité “Réarrangements Thermiques et Photochimiques” Associée au CNRS, Université de Reims Champagne-Ardenne, B.P. 347, 51062, Reims Cedex, France

Pages 1789-1794 | Received 24 Oct 1994, Published online: 23 Sep 2006

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https://doi.org/10.1080/00397919508015421

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Abstract

(S)-2-Cyclopentenyl benzoate has been obtained in 54–67% yield and 54–59% enantiomeric excess (ee) by oxidation of cyclopentene with tert-butyl peroxybenzoate catalyzed by copper(I) oxide and (S)-proline.

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