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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 13
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Original Articles

Dialkylborane-Catalyzed Hydroboration of Alkynes with 1,3,2-Benzodioxaborole in Tetrahydrofuran

A. Arase Department of Industrial Chemistry, Kitami Institute of Technology, Koencho Kitami, 090, Japan
,
M. Hoshi Department of Industrial Chemistry, Kitami Institute of Technology, Koencho Kitami, 090, Japan
,
A. Mijin Department of Industrial Chemistry, Kitami Institute of Technology, Koencho Kitami, 090, Japan
&
K. Nishi Department of Industrial Chemistry, Kitami Institute of Technology, Koencho Kitami, 090, Japan
Pages 1957-1962 | Received 24 Aug 1994, Published online: 23 Sep 2006
 
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Abstract

Dialkylborane catalyzed hydroboration of alkynes with an equimolar amount of 1,3,2-benzodioxaborole in tetrahydrofuran efficiently to provide 2-alkenyl-1,3,2-benzodioxaborole under mild reaction conditions.

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