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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 13
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Original Articles

Synthesis of Cyclopropenone-Containing Amino Acid Mimic. Addition of Cyclopropenyl Cerium Reagent to α-Amino Aldehydes

Hidetoshi Tokuyama Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152, Japan
,
Masahiko Isaka Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152, Japan
&
Eiichi Nakamura Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152, Japan
Pages 2005-2012 | Received 06 Oct 1994, Published online: 23 Sep 2006
 
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Abstract

A novel amino acid mimic, 2-(2-amino-1-hydroxyalkyl)-cyclopropenone, has been prepared via chelation controlled addition of a cyclopropenyl cerium reagent to an α-amino aldehyde.

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