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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 2
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Original Articles

Synthesis of 3-Fluoropyruvates from Glycidic-α-Cyanoesters

I. Chehidi Laboratoire de Chimie Organique Structurale, Faculté des Sciences de Tunis, Campus Universitaire, 1060 Tunis, Tunisie
,
M. M. Chaabouni Ecole Supéricure des Industries Alimentaires, 58, avenue Alain Savary, 1003, Tunis, Tunisie
&
A. Baklouti Laboratoire de Chimie Organique Structurale, Faculté des Sciences de Tunis, Campus Universitaire, 1060 Tunis, Tunisie
Pages 237-241 | Received 19 Jun 1995, Published online: 21 Aug 2006
 
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Abstract

The decyanation of α-cyano-β-fluoro-α-hydroxyesters is achieved, at room temperature, by action of Ni(OAc)2. The corresponding 3-fluoropyruvates are obtained in good yields.

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