Reductive Cleavage of Epoxides with Zinc Borohydride Supported on Aipo₄

Juan M. Campelo Department of Organic Chemistry, University of Cordoba, Avda. S. Alberto Magno, Córdoba, E-14004, Spain

Rupak Chakraborty Department of Organic Chemistry, University of Cordoba, Avda. S. Alberto Magno, Córdoba, E-14004, Spain

Jose M. Marinas Department of Organic Chemistry, University of Cordoba, Avda. S. Alberto Magno, Córdoba, E-14004, Spain

Abstract

Reductive cleavage of styrene oxide and epichlorohydrin to alcohols have been achieved using zinc borohydride supported on AlPO₄. In the styrene oxide reductive cleavage, Zn(BH₄)₂ supported on AlPO₄ is a better catalyst than Zn(BH₄)₂/SiO₂ previously described.

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Reductive Cleavage of Epoxides with Zinc Borohydride Supported on Aipo₄

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Reductive Cleavage of Epoxides with Zinc Borohydride Supported on Aipo4

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Reductive Cleavage of Epoxides with Zinc Borohydride Supported on Aipo₄