Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 3
31
Views
13
CrossRef citations to date
0
Altmetric
Original Articles

A Novel Synthesis of Vinyl Dithiocarbamates via Phosphonium Ylides

&
Pages 509-514 | Received 20 Jul 1995, Published online: 21 Aug 2006
 

Abstract

In the presence of potassium carbonate, N, N-dimethylamino thio-carbonyl thiomethyl triphenylphosphonium bromide can form the corresponding ylide in situ, which can undergo Wittig reaction with aldehydes to give vinyl dithiocarbamates in high yields. If the esters were hydrolysized in the presence of mercuric chloride, a new method to lengthen aldehydes by one carbon atom was accomplished.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.