Oxidation of Alcohols by Silica Gel-Supported bis(Trimethylsilyl) Chromate

Jong Gun Lee Department of Chemistry, College of Natural Sciences, Pusan National University, Pusan, 609–735, Republic of Korea

Jung A Lee Department of Chemistry, College of Natural Sciences, Pusan National University, Pusan, 609–735, Republic of Korea

Soo Yun Sohn Department of Chemistry, College of Natural Sciences, Pusan National University, Pusan, 609–735, Republic of Korea

Abstract

Bis(trimethylsilyl) chromate generated from chromic anhydride and hexamethyldisiloxane in dichloromethane was supported onto silica gel surface. This supported chromium (VI) reagent was excellent for oxidizing alcohols of various types of the corresponding carbonyl compounds.

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Oxidation of Alcohols by Silica Gel-Supported bis(Trimethylsilyl) Chromate

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Oxidation of Alcohols by Silica Gel-Supported bis(Trimethylsilyl) Chromate

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