Convenient Synthesis of Hetero Decalins

S. B. Hadimani Department of Chemistry, Indian Institute of Technology, Powai, Bombay, 400 076, India

R. Padmakumar Department of Chemistry, Indian Institute of Technology, Powai, Bombay, 400 076, India

S. V. Bhat Department of Chemistry, Indian Institute of Technology, Powai, Bombay, 400 076, India

Abstract

A novel synthesis of heterodecalins has been achieved through Baylis-Hillman reaction of 2-formyl-4,4-dimethylcyclohexa-2,5-dien-1-one (1) with unsaturated vinyl systems, followed by allylic migration of hydroxyl group and cyclization or benzyl amine addition to yield the oxa- and aza- decalins respectively.

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Convenient Synthesis of Hetero Decalins

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Convenient Synthesis of Hetero Decalins

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