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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 23
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Original Articles

Stereoselective Synthesis of Versatile Intermediates for Clerodanes Total synthesis

Paul-Henri Ducrot Unité de Phytopharmacie et Médiateurs Chimiques, I.N.R.A. Route de Saint-Cyr, F-78026, Cedex, France
,
Anne-Claire Hervier Unité de Phytopharmacie et Médiateurs Chimiques, I.N.R.A. Route de Saint-Cyr, F-78026, Cedex, France
&
Jean-Yves Lallemand Laboratoire de Synthése Organique de l'Ecole Polytechnique, F-91128, Palaiseau Cedex, France
Pages 4447-4457 | Received 15 Apr 1996, Published online: 23 Aug 2006
 
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Abstract

The stereoselective synthesis of compounds 2a-d, attractive intermediates for the synthesis of clerodane diterpenes is described in 6 to 9 steps in good overall yields from commercially available racemic Wieland-Miescher ketone.

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