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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 23
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Original Articles

Enantioselective Catalytic Borane Reduction of Prochiral Ketones: Synthesis and Application of New Rigid β-Amino Alcohols with a Cycloalkanol Subunit

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Pages 4477-4485 | Received 19 Apr 1996, Published online: 23 Aug 2006
 

Abstract

Enantiocontrolled reduction of prochiral ketones with borane in the presence of new enantiomerically pure bi-and tricyclic β-sec-amino alcohols 2–5 as stereodifferentiating catalysts afforded the optically active corresponding secondary alcohols in moderate to excellent (up to 98 % op) optical yields.

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