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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 13
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Original Articles

Pseudoesters and Derivatives XXXV. Reactions of 4-Substituted-5-(Ethylthio)Furan-2(5H)-Ones Anions with Alkylating Agents

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Pages 2573-2586 | Received 02 Feb 1996, Published online: 23 Aug 2006
 

Abstract

Alkylation of anions derived from 5-ethylthio-4-substituted furanones (1–3) is described. The regioselectivity depends on the alkylating agent but mainly on the nature of the substituent. The alkylation of 4-methoxyfuranone 3 proceeds regioselectively to afford the 5-alkylated derivative as sole product.

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