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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 4
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Original Articles

Stereoselective synthesis of (E)-Vinylic selenides

Xian Huang Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
&
Liu-Sheng Zhu Department of Chemistry, Hangzhou University, Hangzhou, 310028, P. R. China
Pages 671-675 | Received 19 Jun 1995, Published online: 21 Nov 2007
 
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Abstract

1-Alkynes react with Cp2Zr (H)Cl (Cp = η5-C5H5) giving organozirconium(IV) complexes, which are trapped with diaryl diselenides to afford (E)-vinylic selenides.

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