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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 26, 1996 - Issue 4
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Original Articles

Catalytic stereoselective synthesis of α-Amino phosphonic acid derivatives by asymmetric hydrogenation

Ute Schmidt Institut für Organische Katalyseforschung an der Universität Rostock e.V, Buchbinderstr. 5-6, D-18055, Rostock, Germany
,
Günther Oehme Institut für Organische Katalyseforschung an der Universität Rostock e.V, Buchbinderstr. 5-6, D-18055, Rostock, Germany
&
Hanswalter Krause Institut für Organische Katalyseforschung an der Universität Rostock e.V, Buchbinderstr. 5-6, D-18055, Rostock, Germany
Pages 777-781 | Received 24 Jul 1995, Published online: 21 Nov 2007
 
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Abstract

The phosphonate analogue of α-N-benzoyl protected phenylalanine methylester has been prepared by catalytic synthesis. Commonly used Rh-complexes has been applied in asymmetric hydrogenation to check their usefulness in the standard reaction.

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Related Research Data

Catalytic Asymmetric Synthesis of α- and β-Amino Phosphonic Acid Derivatives
Source: Wiley
Enantioselective Synthesis of Optically Active Alkanephos‐ phonates via Rhodium‐Catalyzed Asymmetric Hydrogenation of β‐Substituted α,β‐Unsaturated Phosphonates with Ferrocene‐Based Monophosphoramidite Ligands
Source: Wiley
From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis
Source: Royal Society of Chemistry (RSC)

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