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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 6
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Original Articles

P-C Bond Cleavage of Triethyl 2-Fluoro-3-oxo-2-phosphonoacetates with Magnesium Chloride: A Synthesis of α-Fluoro-β-keto Esters

Dae Young Kim Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97, Chungnam, 336-600, Korea
,
Jin Seok Choi Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97, Chungnam, 336-600, Korea
&
Dae Yong Rhie Department of Chemistry, Soonchunhyang University, Onyang P. O. Box 97, Chungnam, 336-600, Korea
Pages 1097-1103 | Received 19 Aug 1996, Published online: 22 Aug 2006
 
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Abstract

P-C bond cleavage of triethyl 2-fluoro-3-oxo-2-phosphonoacetates in the presence of magnesium chloride provides a synthetic route to α-fluoro-β-keto esters.

Notes

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