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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 16
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Original Articles

A Convenient Method of Meta-Directing Nitration of 3-Substituted Phenol by Lanthanide (III) Nitrates

Shangxiang Gu Department of Chemistry, Lanzhou University, Lanzhou, 730000, China
,
Huanwang Jing Department of Chemistry, Lanzhou University, Lanzhou, 730000, China
,
Jigui Wu Department of Chemistry, Lanzhou University, Lanzhou, 730000, China
&
Yongmin Liang Department of Chemistry, Lanzhou University, Lanzhou, 730000, China
Pages 2793-2797 | Received 27 Mar 1997, Published online: 22 Aug 2006
 
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Abstract

Abstract : Thirteen compounds of 3-substituted phenols were nitrated by lanthanide(III) nitrates in a solution of ethyl acetate. Whether the substituents were ortho-, para-directing groups or meta-directing groups, only one kind nitrated product, 3-substituted-5-nitropenol, and its intermediate were obtained respectively.

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