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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 1
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Original Articles

Asymmetric Synthesis of 4(R)Tert-Butyl-8a(S)Hydroxycarbonyl-4,6,7,8,8a,9-Hexahydro-1-Alkyl-Pyrrolo[3,2-f]Indolizines via Intramolecular Iminium Ion Cyclization

Rita Annunziata Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via G. Venezian, 21, 20133, Milano, Italy
,
Marinella Ferrari Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via G. Venezian, 21, 20133, Milano, Italy
,
Gianluca Papeo Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via G. Venezian, 21, 20133, Milano, Italy
,
Marina Resmini Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via G. Venezian, 21, 20133, Milano, Italy
&
Massimo Sisti Dipartimento di Chimica Organica e Industriale, Università degli Studi di Milano, Via G. Venezian, 21, 20133, Milano, Italy
Pages 23-38 | Received 31 May 1996, Published online: 19 Aug 2006
 
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Abstract

Enantiomerically pure compounds embodying the 4,6,7,8,8a,9-hexahydropyrrolo[3,2-f]indolizine unit were synthesized via intramolecular iminium ion cyclization. An improved procedure for the preparation of the oxazolidinone 1 is also reported.

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