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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 1
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Original Articles

Stereoselective Synthesis of (E)-1,2-Disubstituted Ethenes by Means of Sequential Cross-Coupling Reactions

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Pages 39-44 | Received 05 Jun 1996, Published online: 19 Aug 2006
 

Abstract

The sequential formation of two C-C bonds by reaction of Grignard reagents with (E)-1-halo-2-arylselenoethylenes in the presence of NiCl2(PPh3)2 catalyst provides a stereoselective synthesis of (E)-1,2-disubstituted ethenes in high yield.

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