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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 22
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Original Articles

Application of Alkali Metal Hydrides of Nanometric Size in Reduction, Cyclotrimerization and Metalation

Wenming Zhang Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O.Box 110, Dalian, 116023, P. R. China
,
Shijian Liao Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O.Box 110, Dalian, 116023, P. R. China
,
Yun Xu Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O.Box 110, Dalian, 116023, P. R. China
&
Yiping Zhang Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O.Box 110, Dalian, 116023, P. R. China
Pages 3977-3983 | Received 17 Jun 1997, Published online: 22 Aug 2006
 
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Abstract

Abstract: Reactions of some representative organic functional compounds by the alkali metal hydrides of nanometric size have been studied. Nitrobenzene, some aldehydes, esters and organic halides are reduced with good yield and high selectivity in many cases. Nitriles are cyclotrimerized and dimethyl sulfoxide is rapidly deprotonated.

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