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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 22
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Original Articles

A Convenient Synthesis of 2′- OR 4′-Hydroxycocaine

Satendra Singh Department of Medicinal Chemistry and Pharmaceutics, College of Pharmacy
,
Garo P. Basmadjian Department of Medicinal Chemistry and Pharmaceutics, College of Pharmacy
,
Kwasi Avor Department of Medicinal Chemistry and Pharmaceutics, College of Pharmacy
,
Buddi Pouw Department of Medicinal Chemistry and Pharmaceutics, College of Pharmacy
&
Thomas W. seale Department of Pediatrics, Psychiatry and Behavioral Science, College of Medicine, University of Oklahoma Health Sciences Center, OK, Oklahoma City, 73190, U.S.A.
Pages 4003-4012 | Received 05 Jun 1997, Published online: 22 Aug 2006
 
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Abstract

Abstract: A short, convenient and efficient synthesis of 2′- or 4′-hydroxycocaine is described. The key step involved selective hydrolysis/transesterification of the acetoxy group of 2′- or 4′-acetoxycocaine in methanol saturated with dry HCl gas.

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