One-Pot Preparation of Aroylsilanes by Reductive Silylation of Methyl Benzoates

Emily C. Tongco Donald P. and Katharine B. Loker Hydrocarbon Research Institute and, Department of Chemistry, University of Southern Caifornia, University Park, Los Angeles, CA, 90089-1661

Qunjie Wang Donald P. and Katharine B. Loker Hydrocarbon Research Institute and, Department of Chemistry, University of Southern Caifornia, University Park, Los Angeles, CA, 90089-1661

G. K. Surya Prakash Donald P. and Katharine B. Loker Hydrocarbon Research Institute and, Department of Chemistry, University of Southern Caifornia, University Park, Los Angeles, CA, 90089-1661

Abstract

A one-pot synthesis of aroylsilanes based on reductive silylation of methyl benzoates using Mg/I2/chlorosilane in nontoxic 1-methyl-2-pyrrolidinone (NMP) solvent, is described. The yields are moderate to good and the method has been used for the preparation of some new bifunctional aroylsilanes.

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One-Pot Preparation of Aroylsilanes by Reductive Silylation of Methyl Benzoates

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One-Pot Preparation of Aroylsilanes by Reductive Silylation of Methyl Benzoates

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