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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 27, 1997 - Issue 20
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Original Articles

Synthesis of Chiral 2-Arylpropenoic Esters by the Palladium Catalyzed Carbonylation of Arylacetylenes

Adriano L. Monteiro Grupo de Catálise, Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, CEP 91591—970, Porto Alegre, Brazil
,
Vanusa R. Lando Grupo de Catálise, Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, CEP 91591—970, Porto Alegre, Brazil
&
Vanessa Gasparini Grupo de Catálise, Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, CEP 91591—970, Porto Alegre, Brazil
Pages 3605-3611 | Received 28 Apr 1997, Published online: 22 Aug 2006
 
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Abstract

A simple method is described for the synthesis of chiral 2-arylpropenoic esters by carbonylation of arylacetylenes in the presence of chiral alcohols catalyzed by palladium complexes under mild conditions (10 atm, 100°C, 2h) with high yields.

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