A Convenient Biphasic System (Alumina-Dichloromethane) for the Efficient Aromatic Monochlorination of Alkyl Phenyl Ethers with Sodium Chlorite in the Catalytic Presence of Manganese(III) Salt

Masao Hirano Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, Japan

Shigetaka Yakabe Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, Japan

Hiroyuki Monobe Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, Japan

James H. Clark Department of Chemistry, University of York, Heslington, York, YO1 5DD, UK

Takashi Morimoto Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, Koganei, Tokyo, 184, Japan

Abstract

A combination of sodium chlorite, (salen)manganese(III) catalyst, and chromatographic neutral alumina in dichloromethane can be successfully utilized for the aromatic monochlorination of a variety of alkyl phenyl ethers in excellent to quantitative yields under mild and anhydrous conditions.

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A Convenient Biphasic System (Alumina-Dichloromethane) for the Efficient Aromatic Monochlorination of Alkyl Phenyl Ethers with Sodium Chlorite in the Catalytic Presence of Manganese(III) Salt

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A Convenient Biphasic System (Alumina-Dichloromethane) for the Efficient Aromatic Monochlorination of Alkyl Phenyl Ethers with Sodium Chlorite in the Catalytic Presence of Manganese(III) Salt

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