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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 23
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Original Articles

Studies on the CIS Dihydroxylation of Drimanediene Skeleton

, , &
Pages 4371-4386 | Received 01 Jun 1998, Published online: 23 Aug 2006
 

Abstract

The osmylation of dienic sulfone 4, a potential key intermediate in forskolin 1 and polyhydroxylated drimanes or labdanes derivatives, occurred exclusively on the Δ6–7 double bound and preferentially from the α-face of the molecule (40–100% de). The influence of the substituent at C-1 on the stereoselectivity of the reaction is studied.

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