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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 8
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Original Articles

Preparation of Dehydroabietic Acid and “Dihydroabietic Lactone” by Disproportionation of Tall Oil Rosin with Trifluoroacetic Acid

Kathryn B. Anderson PAPRO New Zealand, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
,
Richard M. Ede Wood Products Division, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
,
Robert A. Franich Wood Products Division, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
,
Hank W. Kroese Wood Products Division, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
,
John A. Lloyd PAPRO New Zealand, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
&
Roger Meder Wood Products Division, New Zealand Forest Research Institute Limited, Rotorua, New Zealand
Pages 1375-1380 | Received 02 Sep 1997, Published online: 22 Aug 2006
 
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Abstract

Dehydroabietic acid 2 and “dihydroabietic lactone” 3 together with an oily mixture of three saturated lactones 4 epimeric with 3 were obtained when Tall Oil diene resin acids (e.g. abietic acid) were disproportionated with trifluoroacetic acid.

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