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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 1
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Original Articles

Trans-Esterification in Dry Media Using Ferric Perchlorate Adsorbed on Silica Gel

Anupama Parmar Department of Chemistry, Sant Longowal Institute of Engg. & Technology, Longowal, 148 106, India
,
Rita Goyal Department of Chemistry, Punjabi University, Patiala, 147 002
,
Baldev Kumar Department of Chemistry, Sant Longowal Institute of Engg. & Technology, Longowal, 148 106, India
&
Harish Kumar Department of Chemistry, Sant Longowal Institute of Engg. & Technology, Longowal, 148 106, India
Pages 139-143 | Accepted 13 Mar 1998, Published online: 17 Sep 2007
 
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Abstract

Adsorption of Fe(C104)3(H20)g onto chromatographic grade silica gel in the presence of ethyl acetate (to be used for trans-esterification) produces a supported reagent, Fe(C10,4)3(EtOAc)6/Si02-This reagent, has been found effective for the rapid and high yield of esters via trans-esterification on grinding in the presence of alcohols/carboxylic acids using pestle and mortar in the solid state.

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