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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 13
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Original Articles

Nickel-Catalyzed Benzylic Oxidation with NaOCl

Shigekazu Yamazaki Toyama Research Laboratory, Toyama Industrial Technology Center, 383 Takada, Toyama, Toyama, 930-0866, Japan
Pages 2211-2216 | Received 06 Oct 1998, Published online: 17 Sep 2007
 
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Abstract

Ni(bpy)2Cl2 has been found to be an efficient catalyst for the oxidation of various alkylbenzenes with hypochlorite. Substituted toluenes having electron withdrawing group at 4-position were oxidized to the corresponding substituted benzoic acids in excellent yields.

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