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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 13
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Original Articles

Tungsten Hexachloride (WCl6), A Highly Efficient and Chemoselective Catalyst for Acetalization of Carbonyl Compounds

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Pages 2255-2263 | Accepted 15 Nov 1998, Published online: 17 Sep 2007
 

Abstract

Various types of aldehydes and ketones could be converted chemoselectively to their corresponding 1,3-dioxanes or diethyl acetals in the presence of catalytic amounts of tungsten hexachloride (WCI6) in good to excellent yields in CH2Cl2 or under neat conditions, respectively.

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