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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 14
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Original Articles

Stereoselective Synthesis of (E)-Vinylsulfides via The Reaction of Vinylzirconium Compounds with Disulfides

Xian Huang Department of Chemistry, Hang zhou University, Hang zhou, 310028, P. R. China
,
Xin-Hua Xu Department of Chemistry, Hang zhou University, Hang zhou, 310028, P. R. China
&
Wei-Xin Zheng Department of Chemistry, Hang zhou University, Hang zhou, 310028, P. R. China
Pages 2399-2404 | Received 19 Jan 1999, Published online: 17 Sep 2007
 
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Abstract

Hydrozirconation of alk-1-ynes gives vinyl zirconium complexes, which react with disulfides to afford (E)-vinylic sulfides in high yield.

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