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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 29, 1999 - Issue 16
156
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Original Articles

Free Radical Cyclizations of Trienes with Tris(Trimethylsilyl)Silane

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Pages 2795-2806 | Received 02 Feb 1999, Published online: 25 Sep 2007
 

Abstract

The intramolecular trapping of a stabilized intermediate allylic radical generated by the addition of tris(trimethylsilyl)silyl (sisyl) radical to a conjugated system was performed. The observed low stereoselectivity suggests thermodynamic rather than kinetic control in this cyclization process.

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