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Abstract
The reaction of hydride polyaddition of methylhydridcsiloxanes to unsaturated carbocyclic compound–dicylopentadiene, at the ratio of initial compounds 1:53 and 1:30, in the presence of platinum chlorohydric acid has been investigated. The hydride poly-addition reaction order, activation energies and rate constants were found. The poly-organosiloxanes with tricyclodecenyl fragment in the side chain, completely dissoluble in organic solvents were synthesized. The synthesized oligomers were characterized by 1H and 13C NMR, IR, thermogravimetric, gel permeation chromatographic, differential scanning calorimetric and X-ray methods.