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Original Articles

Maltose-Containing Polyurethane Films: Synthesis, Characterization, and Their Use for Determination of Dopamine in the Presence of the Electroactive and Nonelectroactive Interferents

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Pages 642-647 | Received 03 Jul 2012, Accepted 26 Dec 2012, Published online: 24 May 2013
 

Abstract

A series of polyurethanes were prepared from the maltose-ethylene glycol-diphenylmethane diisocyanate and used to construct a novel polyurethane electrode for the detection of dopamine. The polyurethanes were characterized by FT-IR, differential scanning calorimetry, and thermogravimetric analysis. The intrinsic viscosity and adhesive properties were also evaluated. Selectivity behaviour of films prepared from polyurethane solutions containing 1%, 3%, 5%, and 10% maltose to electroactive and nonelectroactive substances was examined by DPV. The results demonstrated that polymer electrode by 2 µL polyurethane solutions containing 3% maltose was allowed penetration of dopamine while blocking the permeation of ascorbic acid and uric acid through film.

Acknowledgment

The authors would like to express their appreciation to Inonu University Scientific Research Unit for financial support for this study under grant BAP-2011/14.

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