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International Journal of Polymeric Materials and Polymeric Biomaterials Volume 42, 1998 - Issue 3-4
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Original Articles

Peculiarities of Alumoxanes Formation

Vadim I. Irzhak Institute of Problem Chemical Physics of Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russia
,
Tamara F. Irzhak Institute of Problem Chemical Physics of Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russia
,
Petr E. Matkovski Institute of Problem Chemical Physics of Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russia
,
Ahn Ki Lee Daeduk Research Institute of Honam Petrochemical Corporation, #24-1, Jang-dong,Yooseong-ku, Taejeon-city, 305-343, South Korea
&
Bo Geun Song Daeduk Research Institute of Honam Petrochemical Corporation, #24-1, Jang-dong,Yooseong-ku, Taejeon-city, 305-343, South Korea
Pages 261-273 | Received 08 Jan 1998, Published online: 27 Oct 2006
 
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Abstract

Available experimental data on the processes of alkylalumoxanes formation have been analyzed. During a purposeful study the peculiarities of alkylalumoxanes formation via water hydrolysis of A1R3 were revealed. On the basis of data obtained a simplified kinetic model and a mathematical description of the process under consideration are proposed and presented here.

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