Synthesis and Crystal Structures of Two Nest-Shaped Cluster Compounds, [MoOS₃Cu₃ (SCN)py₅] and [WOS₃Cu₃(SCN)py₅]

Hegen Zheng State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, China

Jinxi Chen State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, China

Xinquan Xin State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, China

Wa-Hung Leung Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong

Maochun Hong State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China

Abstract

The compounds [MOS₃Cu₃ (SCN)X₅] (M = Mo, W; X = py, 4-CH₃py, 4-tert-Bupy) have been prepared by the reaction of (NH₄)₂MO₂S₂ (M = Mo, W), CuSCN and the appropriate ligand X under mild conditions and were characterized by elemental analyses, IR and UV-Vis spectra. Single-crystal X-ray analyses of both compounds reveal that they have a nest-shaped structure and the average M-Cu distances are 2.684(3) Å for M = Mo and 2.693(2) Å for M = W.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Synthesis and Crystal Structures of Two Nest-Shaped Cluster Compounds, [MoOS₃Cu₃ (SCN)py₅] and [WOS₃Cu₃(SCN)py₅]

Information for

Open access

Opportunities

Help and information

Synthesis and Crystal Structures of Two Nest-Shaped Cluster Compounds, [MoOS3Cu3 (SCN)py5] and [WOS3Cu3(SCN)py5]

Abstract

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature

Synthesis and Crystal Structures of Two Nest-Shaped Cluster Compounds, [MoOS₃Cu₃ (SCN)py₅] and [WOS₃Cu₃(SCN)py₅]